Softening

design variants Ι process description Ι examples of use Ι technical data Ι cost of operation Ι further information

Overview

In a softening plant, alkaline earths dissolved within the water will be exchanged with neutral salts via ion exchange. Regeneration is conducted with common salt dilution, once the ion exchange resin has been depleted.

Doppelenthärtungsanlage
Picture: Softener, designed as duplex plant with diaphragm valves, brine dissolving tank.

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Design Variants

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Process Description

During the softening process, alkaline earth ions like calcium (Ca2+) or magnesium (Mg2+) are exchanged for sodium ions (Na+) at the ion exchange resin. For this purpose, the to be softened water flows through the resin bed inside the softening vessel. The actual ion exchange occurs for example according to the formula:

Ca(HCO3)2 + Na2 [resin] → Ca [resin] + 2NaHCO3
MgSO4 + Na2 [resin] → Mg [resin] + Na2SO4

The sodium ions remain within the soft water, for example as sodium bicarbonate (NaHCO3) or sodium sulphate (Na2SO4). Thus, the salt content of the water does not change due to softening. The concentration of alkaline earths can be reduced to < 0.01 mmol/l, which approximately equals a total hardness of < 0.05 °dH.

Once the ion exchange resin is depleted, it needs to be regenerated with common salt (NaCl). This does for example occur according to the formula:

Ca [resin] + 2NaCl → Na2 [resin] + CaCl2

The regeneration effluent, which includes the calcium chloride (CaCl2) and magnesium chloride (MgCl2) formed during the regeneration process, as well as surplus sodium chloride, can be discharged into the sewer system.

Regeneration is triggered and executed fully automated. Depending upon the plant size either quantity-dependant or quality-dependant, by measuring the hardness remaining in the soft water.

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Examples of Use

Picture: Softening plant, flow capacity 8 m³/h, commissioned 2005 in Zörbig, Germany.

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Technical Data

(varies depending upon design and operating conditions)

flow rate: 0.5 ... 200 m³/h
raw water pre-pressure, abs: 2 ... 10 bar
raw water temperature 8 ... 50 °C
up to 120 °C for special applications
raw water quality: pre-filtrated well or surface water
town water
permeate
condensate
service life: 6 ... 24 h
regeneration agent: common salt (NaCl)
soft water quality: total alkaline earths < 0.01 ... 0.1 mmol/l
≈ total hardness < 0.05 ... 0.5 °dH
vessel material: glass-reinforced plastic (grp)
steel (coated)
stainless steel
piping material: PVC
PP
stainless steel
ion exchange medium: ion exchange resin, strongly acidic

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Cost of Operation

Low. Mainly caused by effluent, and salt consumption during regeneration. Accordingly depending upon the hardness of the raw water, as well as the costs of raw water and common salt.

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Further Information

Technical data sheets
Drawings
Questionnaires: Request for tender
References

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